nP = 3.1/31 = 0.1 (mol) 

4P + 5O2 -to-> 2P2O5 

0.1__0.125_____0.05

mP2O5 = 0.05*142 = 7.1 (g) 

VO2 = 0.125 * 22.4 = 2.8 (l)

bạn từng câu lên sẽ dễ nhìn hơn 

PTHH: \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)

a) Ta có: \(n_{KMnO_4}=\dfrac{94,8}{158}=0,6\left(mol\right)\)

\(\Rightarrow n_{O_2\left(lýthuyết\right)}=0,3\left(mol\right)\) \(\Rightarrow n_{O_2\left(thực\right)}=0,3\cdot90\%=0,27\left(mol\right)\)

\(\Rightarrow V_{O_2\left(thực\right)}=0,27\cdot22,4=6,048\left(l\right)\)

b) PTHH: \(4Al+3O_2\underrightarrow{t^o}2Al_2O_3\)

Theo PTHH: \(n_{Al_2O_3}=\dfrac{2}{3}n_{O_2}=0,18\left(mol\right)\)

\(\Rightarrow m_{Al_2O_3}=0,18\cdot102=18,36\left(g\right)\)

\(n_P=\dfrac{6,2}{31}=0,2\left(mol\right)\\ n_{O_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\\ PTHH:4P+5O_2\underrightarrow{t^o}2P_2O_5\\ LTL:\dfrac{0,2}{4}< \dfrac{0,4}{5}\Rightarrow O_2dư\)

\(n_{O_2\left(pư\right)}=\dfrac{5}{4}n_P=\dfrac{5}{4}.0,2=0,25\left(mol\right)\\ n_{O_2\left(dư\right)}=0,4-0,25=0,15\left(mol\right)\)

\(n_{P_2O_5\left(lt\right)}=\dfrac{1}{2}n_P=\dfrac{1}{2}.0,2=0,1\left(mol\right)\\ m_{P_2O_5\left(lt\right)}=0,1.142=14,2\left(g\right)\\ m_{P_2O_5\left(tt\right)}=0,1.142.80\%=11,36\left(g\right)\)

PT: \(2KMnO_4+16HCl\rightarrow2MnCl_2+2KCl+5Cl_2+8H_2O\)

Ta có: \(n_{KMnO_4}=\dfrac{31,6}{158}=0,2\left(mol\right)\)

\(m_{HCl}=\dfrac{60.36,5}{100}=21,9\left(g\right)\Rightarrow n_{HCl}=\dfrac{21,9}{36,5}=0,6\left(mol\right)\)

Xét tỉ lệ: \(\dfrac{0,2}{2}>\dfrac{0,6}{16}\), ta được KMnO₄ dư.

Theo PT: \(n_{Cl_2\left(LT\right)}=\dfrac{5}{16}n_{HCl}=0,1875\left(mol\right)\)

Mà: H% = 80%

\(\Rightarrow n_{Cl_2\left(TT\right)}=0,1875.80\%=0,15\left(mol\right)\)

\(\Rightarrow V_{Cl_2}=0,15.22,4=3,36\left(l\right)\)

Bạn tham khảo nhé!

a.\(n_{KMnO_4}=\dfrac{m}{M}=\dfrac{31,6}{158}=0,2mol\)

\(PTHH:2KMnO_4\underrightarrow{np}K_2MnO_4+MnO_2+O_2\)

                     2                 1                1          1           ( mol )

                   0,2                                             0,1

\(V_{O_2}=n.22,4=0,1.22,4=2,24l\)

b.\(n_{Fe}=\dfrac{m}{M}=\dfrac{11,2}{56}=0,2mol\) 

\(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)

      3         2        1     ( mol )

    0,2      0,1

      0,1    0,1      0,05     ( mol )

\(m_{Fe_3O_4}=n.M=0,05.232=11,6g\)

\(n_{KMnO_4}=\dfrac{15.8}{158}=0.1\left(mol\right)\)

\(2KMnO_4\underrightarrow{t^0}K_2MnO_4+MnO_2+O_2\)

\(n_{O_2}=\dfrac{0.1}{2}=0.05\left(mol\right)\)

\(V_{O_2}=0.05\cdot22.4=1.12\left(l\right)\)

\(b.\)

\(n_P=\dfrac{6.2}{31}=0.2\left(mol\right)\)

\(4P+5O_2\underrightarrow{t^0}2P_2O_5\)

\(4.........5\)

\(0.2........0.05\)

\(LTL:\dfrac{0.2}{4}>\dfrac{0.05}{5}\Rightarrow Pdư\)

\(m_{P\left(dư\right)}=\left(0.2-0.04\right)\cdot31=4.96\left(g\right)\)

PTHH:2KMnO4--- K2MnO4+MnO2 +O2

ADCT nKmno4=15,8/158=0,1 mol 

a, theo pt có nO2/nKmno4= 1/2 

nO2=0,05 mol 

ADCT V=n*22,4 

VO2=0,05*22,4 =1,12 l

b, PTHH: 5O2+4P---2P2O5

ADCTnP=6,2/31=0,2 mol 

Theo pt 

nO2/5=0,01     bé hơn     nP/4=0,05 

P dư 

theo pt nP(pư)/nO2=4/5 

nP(p/ư)=0,04 mol 

nP(dư)=0,05-0,04 =0,01 mol

ADCT:m=n*M

mP(dư)=0,01*31=0,31g

\(n_{KMnO_4}=\dfrac{63,2}{158}=0,4\left(mol\right)\\ pthh:2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
            0,4                                             0,2 
=> \(V_{O_2\left(lt\right)}=0,2.22,4=4,48\left(l\right)\\ V_{O_2\left(tt\right)}=\dfrac{90.4,48}{100}=4,032\left(l\right)\)